Highly Enantioselective Pd-Catalyzed Asymmetric Hydrogenation of N-Diphenylphosphinyl Ketimines Enantioselective Pd-Catalyzed Asymmetric Hydrogenation of N-Diphenylphosphinyl Ketimines

نویسندگان

  • You-Qing Wang
  • Yong-Gui Zhou
چکیده

Transition-metal-catalyzed asymmetric synthesis is a powerful and commonly used method for preparing a wide range of enantiomerically pure compounds.1 Among organo-transition-metal compounds, Pd complexes have become indispensable tools for both common and stateof-the art organic synthesis.2 Although a large number of Pd-based catalytic systems have been developed for many kinds of reactions, Pd chemistry has still not achieved its full potential. So, the search for improved Pd-catalyzed reactions continues with the goal of increasing the diversity of possible substrates and reaction types.

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تاریخ انتشار 2006